cis-Bis[(4-nitrophenyl)cyanamido-κN 1]bis(1,10-phenanthroline-κ2 N,N′)nickel(II) methanol monosolvate
نویسندگان
چکیده
In the title compound, [Ni(C(7)H(4)N(3)O(2))(2)(C(12)H(8)N(2))(2)]·CH(3)OH, the Ni(II) atom is six-coordinated in a distorted N(6) octa-hedral geometry and is chelated by two phenanthroline ligands and two phenyl-cyanamide groups which occupy cis positions. The (4-nitro-phen-yl)cyanamide anions act as monodentate ligands. There is one classical inter-molecular O-H⋯N hydrogen bond and several C-H⋯O hydrogen bonds are also observed.
منابع مشابه
Bis(2-dimethylamino-1,10-phenanthroline-κ2 N,N′)bis(thiocyanato-κN)nickel(II) methanol disolvate
In the title complex, [Ni(NCS)(2)(C(14)H(13)N(3))(2)]·2CH(3)OH, the Ni(II) atom lies on a crystallographic twofold rotation axis and is in a slightly distorted octa-hedral NiN(6) coordination environment. The crystal structure is stabilized by a combination of weak π-π stacking inter-actions between symmetry-related 1,10-phenanthroline ligands [centroi-centroid distance between benzene rings = ...
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The asymmetric unit of the title compound, [Pt(CH(3)CN)(2)(C(12)H(8)N(2))](ClO(4))(2), contains one half of a cationic Pt(II) complex and pair of half perchlorate anions, one of which is disordered over two sites in a 0.53 (3):0.47 (3) ratio. The complex and anions are disposed about a crystallographic mirror plane parallel to the ac plane passing through the Pt and Cl atoms. In the complex, th...
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عنوان ژورنال:
دوره 68 شماره
صفحات -
تاریخ انتشار 2012